
Brookeld Engineering Labs., Inc. Page 74 Manual No. M03-165-F0612
Appendix C - Variables in Viscosity Measurements
As with any instrument measurement, there are variables that can affect a Viscometer measurement.
Thesevariablesmayberelatedtotheinstrument(Viscometer),orthetestuid.Variablesrelatedto
thetestuiddealwiththerheologicalpropertiesoftheuid,whileinstrumentvariableswouldinclude
the Viscometer design and the spindle geometry system utilized.
Rheological Properties
Fluids have different rheological characteristics that can be described by Viscometer measurements.
Wecanthenworkwiththeseuidstosuitourlaborprocessconditions.
Therearetwocategoriesofuids:
Newtonian - TheseuidshavethesameviscosityatdifferentShearRates(differentRPMs)
and are called Newtonian over the Shear Rate range they are measured.
Non-Newtonian - These uids have different viscosities at different shear rates (different
RPMs).Theyfallintotwogroups:
1) Time Independent non-Newtonian
2) Time Dependent non-Newtonian
Time Independent
Pseudoplastic - A pseudoplastic material displays a decrease in viscosity with an increase
in shear rate, and is also known as “shear thinning”. If you take Viscometer
readings from a low to a high RPM and then back to the low RPM, and the
readings fall upon themselves, the material is time independent pseudoplastic
(shear thinning).
Time Dependent
Thixotropic - A thixotropic material has decreasing viscosity under constant shear rate.
If you set a Viscometer at a constant speed recording cP values over time
andndthatthecPvaluesdecreasewithtime,thematerialisthixotropic.
- If you take viscometer readings from a low RPM to a high RPM and then
back to the low RPM, and the readings are lower for the descending step,
the material is time dpendant, thixotropic.
Brookeldpublication,“More Solutions to Sticky Problems” includes a more detailed discussion of
rheological properties and non-Newtonian behavior.
Viscometer Related Variables
Mostuidviscositiesarefoundtobenon-Newtonian.TheyaredependentonShearRate,timeoftest
andthespindlegeometryconditions.ThespecicationsoftheViscometerspindleandchambergeom-
etry will affect the viscosity readings. If one reading is taken at 2.5 rpm, and a second at 50 rpm, the
two cP values produced will be different because the readings were made at different shear rates. The
faster the spindle speed, the higher the shear rate.
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